论文标题
偶极偶极近似中金属纳米颗粒二聚体表面等离子体共振的分析方法
Analytical approach to the surface plasmon resonance characteristic of metal nanoparticle dimer in dipole-dipole approximation
论文作者
论文摘要
这项理论研究涉及两种二聚体中表面等离子体共振(SPR)的影响,其中包括两个相同的金属纳米颗粒(NP)。考虑到drude样模型中的偶极 - 偶极相互作用,为每个NP的介电性得出了适当的方程式。考虑了与源自NP的有限大小的经典限制有关的恢复力,并通过分析实验数据来考虑适当的调整系数。对于激光束电场考虑了两种不同的极化,这表明电场的方向在二聚体的线性光学特性中具有至关重要的作用。对于具有两个不同直径的4nm和20nm的金NP的二聚体,完成了数值研究。对于平行极化,偶极 - 偶极相互作用导致SPR波长的红移并增加其峰值,而对于垂直极化,绝对相反的结果得出了。对于所有情况,可以表明,相对于几何因子$ a/d $(与分离的NP半径)相对于较早的研究表明,相对于相互作用的偶极 - 偶极性特征,可以提出SPR波长功能。从定性上讲,我们的结果与其他实验研究非常吻合。
This theoretical study, deals with the effect of bi-particle interaction on the surface plasmon resonance (SPR) in a dimer which includes two identical metal nanoparticles (NPs). Considering the dipole-dipole interaction in a Drude-like model, an appropriate equation is derived for the permittivity of each NP. The restoration force related to the classical confinement originating from the finite size of NPs is considered and an appropriate adjustment coefficient is considered for this term through analyzing experimental data. Two different polarizations are considered for the laser beam electric field and it is shown that the orientation of electric field has essential role in the linear optical properties of dimer. Numerical investigation is accomplished for a dimer of gold NPs with two different diameters of 4nm and 20nm. For the parallel polarization, dipole-dipole interaction leads to the red-shift of SPR wavelength and increase in its peak value while for the perpendicular polarization, the absolutely opposite results are derived. For all cases, it is shown that SPR wavelength functionality with respect to the geometric factor $a/d$ (NP radius to the separation) can be presented by a cubic equation that fits better than an exponential one suggested by the earlier studies which demonstrates the dipole-dipole characteristic of the interaction. Qualitatively, our results are in good agreement with the other experimental studies.