论文标题

通过瞬态电容测量和原子分辨率化学分析探测的SIO2/4H-SIC接口处的电子捕获

Electron trapping at SiO2/4H-SiC interface probed by transient capacitance measurements and atomic resolution chemical analysis

论文作者

Fiorenza, Patrick, Iucolano, Ferdinando, Nicotra, Giuseppe, Bongiorno, Corrado, Deretzis, Ioannis, La Magna, Antonino, Giannazzo, Filippo, Saggio, Mario, Spinella, Corrado, Roccaforte, Fabrizio

论文摘要

研究与碳化硅(4H-SIC)的栅极氧化物(SIO2)界面的电和结构特性是一个基本主题,对理解和优化金属氧化物 - 氧化物 - 氧化物 - 氧化物 - 导向器场效应晶体管(MOSFET)的性能具有重要意义。在本文中,研究了4H-SIC MOSFET中近界面氧化物陷阱(NIOTS(NIOTS),研究了瞬态栅极电容测量值(C-T)和电子能量损耗光谱(STEM-EELS)中的ART扫描透射电子显微镜的状态与亚NM分辨率。 C-T测量值随温度的函数表明,有效的NIOTS放电时间与温度无关,并且通过调节将NIOT的电子发射到半导体上。同时考虑了隧道弛豫模型中的界面状态密度,对NIOTS的排放时间进行了建模,并允许在距SIO2/4H-SIC接口最高1.3nm的隧道距离内定位陷阱。另一方面,子-NM分辨率干eels揭示了存在非破裂(NA)SIO2/4H-SIC界面的存在。 Na界面显示了亚化学计量学SIOX矩阵中碳原子的重新排列。 Na界面区域中混合的SP2/SP3碳杂交表明,界面碳原子已经失去了四面体SIC协调。

Studying the electrical and structural properties of the interface of the gate oxide (SiO2) with silicon carbide (4H-SiC) is a fundamental topic, with important implications for understanding and optimizing the performances of metal-oxide-semiconductor field effect transistor (MOSFETs). In this paper, near interface oxide traps (NIOTs) in lateral 4H-SiC MOSFETs were investigated combining transient gate capacitance measurements (C-t) and state of the art scanning transmission electron microscopy in electron energy loss spectroscopy (STEM-EELS) with sub-nm resolution. The C-t measurements as a function of temperature indicated that the effective NIOTs discharge time is temperature independent and electrons from NIOTs are emitted toward the semiconductor via-tunnelling. The NIOTs discharge time was modelled taking into account also the interface state density in a tunnelling relaxation model and it allowed to locate traps within a tunnelling distance up to 1.3nm from the SiO2/4H-SiC interface. On the other hand, sub-nm resolution STEM-EELS revealed the presence of a Non-Abrupt (NA) SiO2/4H-SiC interface. The NA interface shows the re-arrangement of the carbon atoms in a sub-stoichiometric SiOx matrix. A mixed sp2/sp3 carbon hybridization in the NA interface region suggests that the interfacial carbon atoms have lost their tetrahedral SiC coordination.

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