论文标题
手性的极化
Polarization of chirality
论文作者
论文摘要
长期以来,人们已经认识到,分子中电子云的空间极化以及原子在手性分子结构中的空间排列在物理,化学和生物学中起着至关重要的作用。但是,到目前为止,这两个基本概念 - 手性和两极分化 - 仍然无关。这项工作通过引入和探索手性极化的概念来将它们联系起来。我们表明,像电荷,手性或惯用性一样,可以极化,这种极化会导致基本后果,在这里使用光证明。首先,我们分析了手性偶极子和高阶手性多物如何在实验性观察物中表现出来。接下来,我们将展示如何在空间中创建手性偏置的光场。尽管是精神,但这些极端时空光结构与手性相反的物质以及光控制的手性偶极子的相互作用不同,并量化了对映体敏感反应的强度。使用非线性相互作用,我们可以制作一种随机定向的手性分子的介质,取决于分子的触及性和光的手性偶极子。排放方向上的手性二分性能达到其200%的最高值。我们的工作打开了手性的光学塑造领域的光和新机会,以有效的手性歧视和控制手性和手性极化光以及超快时间尺度上的物质。
It has been long recognized that the spatial polarization of the electronic clouds in molecules, and the spatial arrangements of atoms into chiral molecular structures, play crucial roles in physics, chemistry and biology. However, these two fundamental concepts - chirality and polarization - have remained unrelated so far. This work connects them by introducing and exploring the concept of polarization of chirality. We show that, like charge, chirality, or handedness, can be polarized, and that such polarization leads to fundamental consequences, demonstrated here using light. First, we analyze how chirality dipoles and higher-order chirality multipoles manifest in experimental observables. Next, we show how to create chirality-polarized optical fields of alternating handedness in space. Despite being achiral, these racemic space-time light structures interact differently with chiral matter of opposite handedness, and the chirality dipole of light controls and quantifies the strength of the enantio-sensitive response. Using nonlinear interactions, we can make a medium of randomly oriented chiral molecules emit light to the left, or to the right, depending on the molecular handedness and on the chirality dipole of light. The chiral dichroism in emission direction reaches its highest possible value of 200%. Our work opens the field of chirality polarization shaping of light and new opportunities for efficient chiral discrimination and control of chiral and chirality-polarized light and matter on ultrafast time scales.