论文标题

评论“反应系统中路径热力学的有效性”

Comment on "Validity of path thermodynamics in reactive systems''

论文作者

Gaspard, Pierre

论文摘要

Malek Mansour和Garcia的论文[Phys。 E 101,052135(2020)]被证明是基于反应性系统中化学热力学的随机配方中的误解。他们的错误主张断言,每当反应性系统涉及多种基本反应导致相同组成变化时,就无法使用路径概率正确评估熵产生。

The paper by Malek Mansour and Garcia [Phys. Rev. E 101, 052135 (2020)] is shown to be based on misconceptions in the stochastic formulation of chemical thermodynamics in reactive systems. Their erroneous claims, asserting that entropy production cannot be correctly evaluated using path probabilities whenever the reactive system involves more than one elementary reaction leading to the same composition changes, are refuted.

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