论文标题

集体弹性在硬球体流体和胶体悬浮液中的激活结构松弛,产量和稳态流动的作用

The Role of Collective Elasticity on Activated Structural Relaxation, Yielding and Steady State Flow in Hard Sphere Fluids and Colloidal Suspensions Under Strong Deformation

论文作者

Ghosh, Ashesh, Schweizer, Kenneth S.

论文摘要

从理论上讲,我们在非平衡版本的弹性集体非线性Langevin方程(ECNLE)理论的背景下,玻璃状硬球体流体的非线性机械响应激活结构弛豫和基本方面的影响。 Ecnle理论将激活的松弛描述为涉及局部笼子和较长范围的集体弹性的局部非局部事件,随着包装分数的增加,后者变得越来越重要。核心的新问题是这种物理图片以及笼子与弹性物理的相对重要性如何取决于外部压力,应变和剪切率。提出了理论预测,用于变形,以提高活动能力,放松速度的发作,压力,应变或无量纲的剪切速率的较低值,结构性放松时间的稀疏以及明显的功率法规的粘度和粘度与明显的功率法规的粘度,剪切状态的不断增长的强调,源于赫尔氏脉冲的增长速率的不断增长,与赫尔氏脉冲的增长效果相稳定,源于源头的增长,源于源头的依赖性,这是源于源头的稳定速度,源于源头的依赖性,源于源头的稳定速率,是源于源头的依赖性效果,源于源头的依赖性效果。填充分数,减少变形的动态脆弱性和异质性。结果与实验和模拟形成鲜明对比,并找到定性或更好的一致性。一个总体的结论是,变形强烈降低了大多数(但不是全部)物理问题的较长范围集体弹性效应的重要性,而压力依赖性的动态异质性现象对集体弹性质量敏感。总体而言,非线性流变学是一个比静态释放的局部笼子量表问题,尽管它具有变形修饰的活化过程仍然很重要。

We theoretically study the effect of external deformation on activated structural relaxation and elementary aspects of the nonlinear mechanical response of glassy hard sphere fluids in the context of the nonequilibrium version of the Elastically Collective Nonlinear Langevin Equation (ECNLE) theory. ECNLE theory describes activated relaxation as a coupled local-nonlocal event involving local caging and longer range collective elasticity, with the latter becoming more important with increasing packing fraction. The central new question is how this physical picture, and the relative importance of caging versus elasticity physics, depends on external stress, strain and shear rate. Theoretical predictions are presented for deformation induced enhancement of mobility, onset of relaxation speed up at remarkably low values of stress, strain or dimensionless shear rate, thinning of the structural relaxation time and viscosity with apparent power law exponents, a non-vanishing activation barrier in the shear thinning regime, a Herschel-Bulkley form of rate dependence of the steady state shear stress, exponential growth of dynamic yield stresses with packing fraction, and reduced dynamic fragility and heterogeneity under deformation. The results are contrasted with experiments and simulations, and qualitative or better agreement is found. An overarching conclusion is that deformation strongly reduces the importance of longer range collective elastic effects for most, but not all, physical questions, with stress-dependent dynamic heterogeneity phenomena being qualitatively sensitive to collective elasticity. Overall, nonlinear rheology is a more local cage scale problem than quiescent relaxation, albeit with deformation-modified activated processes still important.

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