论文标题

周期性金属谐振链,用于表面增强的拉曼散射(SER)

Periodic metal resonator chains for Surface Enhanced Raman Scattering (SERS)

论文作者

Sievers, Jan, Heyroth, Frank, Schlenker, Sven, Schmidt, Georg, Sprafke, Alexander, Below, Marcel, Reinhardt, Carsten, Schilling, Jörg

论文摘要

金盘链的周期性排列显示出明显的等离子光栅共振。这些对4-甲基苯甲醇分子的表面增强的拉曼散射(SERS)的信号具有明显影响,这些分子在金表面上形成自组装的单层:除了清晰的极化依赖性外,SERS-Spectra除了在激发激光波长与plamonic Gramonic Gramonic Graming Grating Resonance匹配时,还表现出最大值。这些特征是通过单个等离子偶极子的近外和远场耦合来解释的,该偶极允许设计优化的纳米结构以实现有效的SERS-SUBSTRATES。

A periodic arrangement of chains of gold discs shows pronounced plasmonic grating resonances. These have a clear impact on the Surface Enhanced Raman Scattering (SERS)-signal from 4-methylbenzenethiol molecules which form self-assembled monolayers on the gold surface: Besides a clear polarisation dependence the SERS-spectra also exhibit a maximum when the excitation laser wavelength matches the plamonic grating resonance. These features are explained by a combined near and far field coupling of the individual plasmonic dipoles allowing the design of optimized nanostructures for effective SERS-substrates in the future.

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