论文标题

Pani织物与等离子纳米结构的增强的太阳光热效应

Enhanced solar photothermal effect of PANi fabrics with plasmonic nanostructures

论文作者

Nga, Do T., Phan, Anh D., Lam, Vu D., Woods, Lilia M., Wakabayashi, Katsunori

论文摘要

使用基于热扩散方程的模型研究了悬挂和浮动聚苯胺(PANI)织物中的光热能转化。湿悬挂的泛孔织物的完美吸收和抗反射会导致总入射光快速转移到限制阳光的近100美元的水中。结果,发现悬挂的膜具有比水面上方的浮动性更具吸引力的特性。但是,我们发现,通过将锡纳米颗粒分散在织物下方的水中,可以大大增强浮动棉膜的光热性能。锡纳米颗粒溶液的计算得出的温度梯度表明,吸收的能量随纳米颗粒密度的增加而生长,并且光热过程主要发生在表面附近。集体加热效应取决于纳米颗粒的大小和密度,该纳米颗粒的大小和密度可以进一步用于调节光热过程。

The photothermal energy conversion in hanging and floating polyaniline (PANi)-cotton fabrics is investigated using a model based on the heat diffusion equation. Perfect absorption and anti-reflection of wet hanging PANi-cotton fabrics cause quick transfer of total incident light into water confining nearly 100 $\%$ of the sunlight. As a result, a hanging membrane is found to have more attractive properties than a floating above water fabric. We find, however, that the photothermal properties of a floating PANi-cotton membrane can greatly be enhanced by dispersing TiN nanoparticles in the water below the fabric. The calculated temperature gradients for TiN nanoparticle solutions show that the absorbed energy grows with increasing the nanoparticle density and that the photothermal process occurs mostly near the surface. The collective heating effects depend on the size and density of nanoparticles, which can further be used to modulate the photothermal process.

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