论文标题

从流过多孔介质的流体中传播

Mass transfer from a fluid flowing through a porous media

论文作者

Myers, T. G., Font, F.

论文摘要

开发了一个数学模型,用于从流过包装柱的流体的传质过程。无论是通过吸收还是吸附,质量损失都可能很重要。例如,从烟气中去除污染物时,这是合适的。由于质量损失很小,模型将减少到更简单的形式,该形式适合描述从液体中去除污染物/污染物的形式。进行了一个案例研究,以从经过活化碳的气体混合物中去除二氧化碳。使用实验参数值,通过非限制化表明,某些术语可以从管理方程式中忽略,从而导致可以使用行动波替代进行分析求解的形式。可以描述整个列中的所有重要数量。气态材料的浓度,可用于传质的材料量,流体速度和压力。通过与突破性曲线的实验数据进行比较(在圆柱插座上测得的碳量)来验证结果。分析表达的优点比纯数值解决方案可以轻松地用于优化过程。在最后一部分中,我们证明了如何去除少量污染物时如何进一步降低模型。与从水中去除阿莫西林和刚果红色染料的实验数据相比,该模型表现出比确定模型更好的一致性。

A mathematical model is developed for the process of mass transfer from a fluid flowing through a packed column. Mass loss, whether by absorption or adsorption, may be significant. This is appropriate for example when removing contaminants from flue gases. With small mass loss the model reduces to a simpler form which is appropriate to describe the removal of contaminants/pollutants from liquids. A case study is carried out for the removal of CO2 from a gas mixture passing over activated carbon. Using the experimental parameter values it is shown, via non-dimensionalisation, that certain terms may be neglected from the governing equations, resulting in a form which may be solved analytically using a travelling wave substitution. From this all important quantities throughout the column may be described; concentration of gaseous materials, amount of material available for mass transfer, fluid velocity and pressure. Results are verified by comparison with experimental data for the breakthrough curve (the amount of carbon measured at the column outlet). The advantage of the analytical expression over a purely numerical solution is that it can easily be used to optimise the process. In the final section we demonstrate how the model may be further reduced when small amounts of contaminant are removed. The model is shown to exhibit better agreement than established models when compared to experimental data for the removal of amoxicillin and congo red dye from water.

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