论文标题

观察负离子中电四极转变:实验和理论

Observation of an electric quadrupole transition in a negative ion: Experiment and Theory

论文作者

Walter, C. W., Spielman, S. E., Ponce, R., Gibson, N. D., Yukich, J. N., Cheung, C., Safronova, M. S.

论文摘要

已经对原子负离子的界面状态之间的第一个直接实验观察($ \ textit {e} $ 2)过渡。通过bi $^ - $ $^3 \ textit {p} _2 $的谐振剂通过bi $^ - $^ - $ $^3 \ textit {p} _0 $ fextit {p} _0 $良好的结构状态,在bi $^ - $ $^3 \ textit {p} _2 $中观察到了过渡。 $ \ textit {e} $ 2过渡属性是使用混合理论方法独立计算的,以说明强大的多级电子相互作用和相对论效应。实验和理论结果非常同意,为这一复杂系统提供了宝贵的新见解,并在负离子中禁止过渡。

The first direct experimental observation of an electric quadrupole ($\textit{E}$2) transition between bound states of an atomic negative ion has been made. The transition was observed in the negative ion of bismuth by resonant (1+1) photodetachment from Bi$^-$ $^3\textit{P}_2$ via excitation of the Bi$^-$ $^3\textit{P}_0$ fine structure state. The $\textit{E}$2 transition properties were independently calculated using a hybrid theoretical approach to account for the strong multi-level electron interactions and relativistic effects. The experimental and theoretical results are in excellent agreement, providing valuable new insights into this complex system and forbidden transitions in negative ions.

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