论文标题

PFG NMR时间依赖性扩散系数分析受限制的乳液:排水后构象

PFG NMR time-dependent diffusion coefficient analysis of confined emulsion: post drainage phase conformation

论文作者

Chencarek, B., Nascimento, M., Souza, A. M., Sarthour, R. S., Coutinho, B., Correia, M. D., Oliveira, I. S.

论文摘要

在这项工作中,我们通过分析从一维脉冲场梯度核能磁共振(PFG NMR)测量值,前后排水量,通过分析时间相关的扩散系数(PFG NMR),通过分析时间相关的扩散系数来表征水饱和烧结的玻璃珠样品中的相位构型。将样品比率的估计值和水饱和样品中的排水前PFG测量值的渗透性分别与分析和报告的值进行了比较,并且在这两种情况下都发现了公平的一致性。从PFG测量结果提取的扩散系数的短时分析用于量化排水后润湿阶段探测的表面体积比的增加。使用Bi-Gaussian模型对排水后PFG实验的水和油扩散系数进行分析,并考虑了两种不同的情况来描述孔内的液体构象。对于认为非润湿阶段表现出不良连接的几何形状的情况,假设执行了孔内的OI中水滴的形成,并确定了液滴radii的高斯分布。

In this work, we present a characterization of phase configuration in water-saturated sintered glass bead samples after oil injection, through the analysis of time-dependent diffusion coefficients obtained from sets of one-dimensional pulsed field gradient nuclear magnetic resonance (PFG NMR) measurements, pre and post drainage. Estimates of samples surface-to-volume ratio and permeability from pre drainage PFG measurements in a water-saturated sample were compared with analytical and reported values, respectively, and a fair agreement was found in both cases. Short-time analysis of diffusion coefficients extracted from PFG measurements was used to quantify the increase in surface-to-volume ratio probed by the wetting phase after drainage. Analysis of water and oil diffusion coefficients from post drainage PFG experiments were carried out using a bi-Gaussian model, and two distinct scenarios were considered to describe fluids conformation within pores. For the case where non-wetting phase was considered to exhibit a poorly connected geometry, an analysis assuming the formation of oi-in-water droplets within pores was performed, and a Gaussian distribution of droplets radii was determined.

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