论文标题

半导体单层中的深色激子可视化高敏性应变感应

Visualization of dark excitons in semiconductor monolayers for high-sensitivity strain sensing

论文作者

Chand, Saroj B., Woods, John M., Mejia, Enrique, Taniguchi, Takashi, Watanabe, Kenji, Grosso, Gabriele

论文摘要

过渡金属二核苷(TMDS)是分层材料,具有半导体相具有许多有利的光电特性,包括紧密结合的激子和自旋valley锁定。在基于钨的TMD中,自旋和动量禁止过渡会产生深色激子,通常是光学上无法访问的,但代表了系统中最低的激子状态。深色激子可以深深影响明亮激烈激子的运输,动力和连贯性,阻碍设备的性能。因此,至关重要的是创建可以看到和控制这些激子状态的条件。在这里,我们表明WS2中的压缩应变使光激动的电子在动量山谷之间的声子散射,从而增强了深色间隔激子的形成。我们表明,动量填充激烈的激子的发射和光谱特性是可以访问的,并且很大程度上取决于修饰带对齐的局部应变环境。在二维半导体中,该机制进一步利用了应变感应,揭示了超过10^4的规格因子。

Transition metal dichalcogenides (TMDs) are layered materials that have a semiconducting phase with many advantageous optoelectronic properties, including tightly bound excitons and spin-valley locking. In Tungsten-based TMDs, spin and momentum forbidden transitions give rise to dark excitons that typically are optically inaccessible but represent the lowest excitonic states of the system. Dark excitons can deeply affect transport, dynamics and coherence of bright excitons, hampering device performance. Therefore, it is crucial to create conditions in which these excitonic states can be visualized and controlled. Here, we show that compressive strain in WS2 enables phonon scattering of photoexcited electrons between momentum valleys, enhancing the formation of dark intervalley excitons. We show that the emission and spectral properties of momentum-forbidden excitons are accessible and strongly depend on the local strain environment that modifies the band alignment. This mechanism is further exploited for strain sensing in two-dimensional semiconductors revealing a gauge factor exceeding 10^4.

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