论文标题

挤压金属液滴,具有可调kubo间隙和过渡金属二分法中的电荷注入

Squeezed metallic droplet with tunable Kubo gap and charge injection in transition metal dichalcogenides

论文作者

Yuan, Jiaren, Chen, Yuanping, Xie, Yuee, Zhang, Xiaoyu, Rao, Dewei, Guo, Yandong, Yan, Xiaohong, Feng, Yuanping, Cai, Yongqing

论文摘要

将散装金属的尺寸缩小到纳米级,导致电子能级的离散性,即所谓的库博间隙。具有可调型和尺寸依赖性的kubo间隙的电子性质重新归一化,使光子发射和电子隧道引人入胜。与通常的三维金属簇相反,在这里我们证明,可以通过二维(2D)金属过渡金属二甲酸酯(即1T'-phase Mote2)纳米簇嵌入半导体polymph(i.e.e.e.e.,1h-------------------------------- i.e.e.e.e.,1h-------------------这样的1T'-1H MOTE2纳米域类似于在2D空间中挤压的3D金属液滴,该液滴显示出强大的极化灾难,同时保持其键完整性,而传统的Delta Gappaper 3D群集则不存在。主机2D MOTE2的较弱筛选导致这种伪金属系统的光子发射,并在1T'-1H-1T'同型中注射载体的弹道注射,这些载体可能会在传感器和2D可重新配置的设备中找到应用。

Shrinking the size of a bulk metal into nanoscale leads to the discreteness of electronic energy levels, the so-called Kubo gap. Renormalization of the electronic properties with a tunable and size-dependent Kubo gap renders fascinating photon emission and electron tunneling. In contrast with usual three-dimensional (3D) metal clusters, here we demonstrate that Kubo gap can be achieved with a two-dimensional (2D) metallic transition metal dichalcogenide (i.e., 1T'-phase MoTe2) nanocluster embedded in a semiconducting polymorph (i.e., 1H-phase MoTe2). Such a 1T'-1H MoTe2 nanodomain resembles a 3D metallic droplet squeezed in a 2D space which shows a strong polarization catastrophe while simultaneously maintains its bond integrity which is absent in traditional delta-gapped 3D clusters. The weak screening of the host 2D MoTe2 leads to photon emission of such pseudo-metallic systems and a ballistic injection of carriers in the 1T'-1H-1T' homojunctions which may find applications in sensors and 2D reconfigurable devices.

扫码加入交流群

加入微信交流群

微信交流群二维码

扫码加入学术交流群,获取更多资源