论文标题
质子耦合电子转移的阳离子依赖性非绝热性在电气固液界面处
Cation-Dependent Nonadiabaticity in Proton-Coupled Electron Transfer at Electrified Solid-Liquid Interfaces
论文作者
论文摘要
在这里，我们报告在质子耦合电子传递电极过程（PCET）中，在AU（111）单晶（111）单晶电极和电解质的电解质上，通过使用电化学动力学分析在超级良好/良好定义的量化系统上，在AU（111）单晶（111）单晶（111）单晶（111）单晶电极和电解质上观察了阳离子依赖性的非绝热性。
Here we report an observation of cation-dependent nonadiabaticity in a proton-coupled electron transfer electrode process (PCET) during hydrogen evolution at electrified interfaces of Au(111) single-crystal electrode and electrolytes by employing electrochemical kinetic isotope effect analysis at ultra-clean/well-defined systems to investigate quantum-to-classical transition (QCT) in highly accuracy.
