论文标题

2D材料中Trions库仑散射的理论

Theory for Coulomb scattering of trions in 2D materials

论文作者

Song, Kok Wee, Chiavazzo, Salvatore, Shelykh, Ivan A., Kyriienko, Oleksandr

论文摘要

我们对Trions(带电激子)之间的库仑相互作用进行了理论描述,该库仑相互作用定义了掺杂的二维半导体中的非线性光学响应。首先,我们根据这些粒子的复合性质制定了Trion-Trion相互作用的微观理论,并解释了所有可能的交换过程。接下来,我们使用具有高表达性的基集来计算数字计算TRION结合能和相应的三体波函数。然后,使用获得的波函数,我们计算两次散射的矩阵元素,并比较来自直接和交换项的贡献。最后,我们发现所考虑的散射对过渡金属二色源单一单层的光学非线性有显着贡献。特别是,这可能会导致掺杂的单层中有吸引力的相互作用。我们的理论为研究Trion-Polaritons的非线性特性开辟了一条途径。

We develop a theoretical description of Coulomb interactions between trions (charged excitons) that define a nonlinear optical response in doped two-dimensional semiconductors. First, we formulate a microscopic theory of trion-trion interactions based on composite nature of these particles, and account for all possible exchange processes. Next, we calculate numerically the trion binding energies and corresponding three-body wavefunctions using a basis set with high expressivity. Then, using the obtained wavefunctions we calculate the matrix elements of two-trion scattering, and compare the contributions coming from direct and exchange terms. Finally, we find that the considered scattering gives significant contribution to the optical nonlinearity in monolayers of transition metal dichalcogenides. In particular, this can lead to an attractive interaction in doped monolayers. Our theory opens a route for studying nonlinear properties of trion-polaritons inaccessible before.

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