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We undertake a study of conic bundle threefolds $π\colon X\to W$ over geometrically rational surfaces whose associated discriminant covers $\tildeΔ\toΔ\subset W$ are smooth and geometrically irreducible. First, we determine the structure of the group $\mathrm{CH}^2 X_{\overline{k}}$ of rational equivalence classes of curves. Precisely, we construct a Galois-equivariant group homomorphism from $\mathrm{CH}^2X_{\overline{k}}$ to a group scheme associated to the discriminant cover $\tildeΔ\to Δ$ of $X$. The target group scheme is a generalization of the Prym variety of $\tildeΔ\toΔ$ and so our result can be viewed as a generalization of Beauville's result that the algebraically trivial curve classes on $X_{\overline{k}}$ are parametrized by the Prym variety. We apply our structural result on curve classes to study the refined intermediate Jacobian torsor (IJT) obstruction to rationality introduced by Hassett--Tschinkel and Benoist--Wittenberg. The first case of interest is $W = \mathbb P^2$ and $Δ$ is a smooth plane quartic. In this case, we show that the IJT obstruction characterizes rationality when the ground field has less arithmetic complexity (precisely, when the $2$-torsion in the Brauer group of the ground field is trivial). We also show that a hypothesis of this form is necessary by constructing, over any $k \subset\mathbb R$, a conic bundle threefold with $Δ$ a smooth quartic where the IJT obstruction vanishes, yet $X$ is irrational over $k$.